676525-77-2|[Ir(dtbbpy)(ppy)2][PF6]

Taw qhia
[Ir(dtbbpy)(ppy)2][PF6] yog cov duab catalyst.

Specification of CAS: 676525-77-2 [Ir(dtbbpy)(ppy)2][PF6]

Synthesis ntawmCAS: 676525-77-2 [Ir(dtbbpy)(ppy)2][PF6]

Theem #1: [iridium(III)(μ-chloro)(2-phenylpyridine)2]2; 4,4'-di-tert-butyl-2,2'-bipyridine Hauv ethylene glycol ntawm 150 degree; rau 15h; Inert cua;

Theem #2: ammonium hexafluorophosphate Hauv dej

Cov txheej txheem sim:

Kev sib nqus sib nqus ntawm 4,4'-di-tert-butyl-2,2'-dipyridyl (118 mg, 0.44 mmol) thiab tetrakis (2-phenylpyridine-C2, N') (μ-dichloro)-diiridium (214 mg, 0.2 mmol) hauv 10 mL ntawm 1, 2-ethanediol nyob rau hauv nitrogen tau rhaub rau 150 degree . Qhov sib tov tau khaws cia ntawm qhov kub no rau 15 teev. Tag nrho cov khib nyiab yaj kom tawm los ua kom pom tseeb, xim daj. Tom qab txias qhov sib tov rau hauv chav tsev kub, 150 mL dej ntxiv. Qhov ntau dhau ntawm bipyridine ligand raug tshem tawm los ntawm peb qhov kev rho tawm nrog diethyl ether (50 mL), thiab cov txheej txheem dej tau tom qab rhuab mus rau 60-70 degree . NH4PF6 (1 g) hauv 10 mL dej tau ntxiv, thiab PF6 ntsev ntawm chromophore tam sim ntawd precipitated. Tom qab txias qhov kev ncua mus rau 5 degree, cov khoom daj tau muab cais los ntawm kev pom, qhuav, thiab recrystallized los ntawm acetonitrile / ether diffusion. Cov zis: 280 mg (77 feem pua).

Cim npe nrov: 676525-77-2,cas 676525-77-2,[ir(dtbbpy)(ppy)2][pf6], nqe, hais, luv nqi, hauv Tshuag, muag