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CAS: 14647-23-5|[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)
Cov mis mos molecular: C26H24Cl2NiP2
Molecular Luj: 528.02
Purity: 98 feem pua
Pob: 5g / 10g / 25g / 50g / bulk pob
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Lub npe | [1,2-Bis(diphenylphosphino)ethane]dichloronickel(II) |
Synonyms | 1, 2-Bis-(Diphenylphosphino) EthaneDichloroNickel;1,2-Bis-(Diphenylphosphino)Eth |
CAS | 14647-23-5 |
MDL Nr | TIAB SA 00013313 |
Boiling Point | 514.8ºC ntawm 760 mmHg |
Melting Point | 263-265 degree (lit.) |
Flash Point | 281.7ºC |
PSA | 27.18 |
Qhov tshwm sim | Yellow rau xim av hmoov, siv lead ua thiab / los yog chunks |
rhiab heev | Moirhiab heev |
Solubility | Chloroform, Methanol (Sparingly) |
Vapor Siab | 3.38E-10mmHg ntawm 25 degree |
Kev cia khoom | Khaws rau hauv qhov chaw txias. Khaws lub thawv kaw kom nruj rau hauv qhov chaw qhuav thiab qhov cua zoo |
Daim ntawv thov:Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II)(CAS: 14647-23-5) yog ib qho reactant koom nrog Kumada catalyst-hloov polycondensation, oxidation ntawm carboranyl phosphine ligands, synthesis ntawm nickel-hlau dithiolato hydrides, Ullmann cov tshuaj tiv thaiv - homocoupling cov tshuaj tiv thaiv, co-catalyst rau hydroformylation ntawm cawv rau lub synthesis ntawm carbon catalyst, quaternary catalyst. - hom intramolecular aerobic oxidative amination ntawm alkenes.
Cov ntaub ntawv:
Bryan E Barton; C Matthew Whaley; Thomas B Rauchfuss; Danielle L Grey Nickel-hlau dithiolato hydrides cuam tshuam rau [NiFe]-hydrogenase active site. Phau ntawv Journal ntawm American Chemical Society. 2009, 131 (20), 6942-6943.
Yusuke Ueki; Hideto Nws; Ua Tsaug Ntau; Bernhard Breit. Tsim cov quaternary carbon centre los ntawm regioselective hydroformylation heev nrog catalytic nqi ntawm ib pawg reversibly bound directing. Chemistry: Phau ntawv European. 2011, 17 (31), 8555-8558.
Cim npe nrov: cas:14647-23-5|[1,2-bis(diphenylphosphino)ethane]dichloronickel(ii), nqe, hais, luv nqi, hauv Tshuag, muag
