CAS: 1100-88-5|Benzyltriphenylphosphonium Chloride (BPP)
Cov mis mos molecular: C25H22ClP
Molecular Luj: 388.87
EINECS:214-154-3
Purity: 99 feem pua
Pob: 5g / 10g / 25g / 50g / bulk pob
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Lub npe | Tom ntej: Benzyltriphenylphosphonium Chloride (BPP) |
Synonyms | BTPPC; GM 200; NSC 116712; Triphenylbenzylphosphonium Chloride; |
MDL Nr | PAB 00011913 |
Melting point | Ntau tshaj lossis sib npaug li 300 degree (lit.) |
Flash Point | 300 degree |
Qhov ntom | 1.18g / cm3 (20 degree) |
PSA | 13.59 |
LogP | 2.18 |
Qhov tshwm sim | Dawb khoom |
rhiab heev | Lub teeb & Moisture rhiab heev |
Solubility (soluble hauv) | Acetone, Methanol, Dej |
Kev ruaj ntseg | ruaj khov. Incompatible nrog muaj zog oxidizing neeg sawv cev |
HS Code | 29310095 |
Vapor Siab | 0.1 hPa |
Kev cia khoom | Khaws nyob rau hauv inert gas. Khaws kom deb ntawm cov oxidizing muaj zog, dej / noo noo |
InChI | InChI=1S/C25H22P.ClH/c1-5-13-22(14-6-1)21-26(23-15-7-2-8-16-23,24-17-9-3-10-18-24)25-19-11-4-12-20-25;/ h1-20H,21H2;1H/q plus 1;/p{14}} |
InChIKey | USFRYJRPHFMVBZ-UHFFFAOYSA-M |
Luag ntxhi | C1=CC=C(C=C1)C[P plus](C2=CC=CC=C2)(C 3=CC=CC=C3)C4=CC=CC=C4.[Cl-] |
Daim ntawv thov:
Benzyltriphenylphosphonium chloride hmoov(CAS: 1100-88-5)yog siv los ua tus accelerator ntawm Bisphenol AF curing system rau fluoroelastomer. Kuj tseem siv los ua theem-hloov catalysts hauv kev sib txuas ntawm qee cov organic tebchaw. Nws yog siv los ua ib qho reactant rau kev sib txuas ntawm cov tshuaj sib txuas.
Literature References:
James McNulty; David McLeod. Amine- thiab sulfonamide-promoted Wittig olefination cov tshuaj tiv thaiv hauv dej. Chemistry: Phau ntawv European. 2011, 17 (32), 8794-8798.
GI Mukhayer; SS Davis. Kev sib cuam tshuam ntawm cov organic ions loj ntawm cov nqi sib txawv: VI. Coacervation hauv kev sib xyaw ntawm sodium dodecyl sulfate thiab benzyltriphenylphosphonium chloride. Phau ntawv Journal of Colloid thiab Interface Science. Xyoo 1978, 66 (1), 110-117.
Wittig olefination nrog carbonyl compounds tuaj yeem ua tau raws li hauv paus, 2-theem mob; phosphonium ntsev ua raws li nws tus kheej theem-hloov catalyst: Synthesis, 295 (1973). Saib Ntxiv Ntxiv 1.
Benzylidene triphenylphosphoranes (tsim nrog n-BuLi) yog ua ke los ntawm cov tshuaj tiv thaiv nrog sulfur los muab stilbenes, nrog tshem tawm ntawm triphenylphosphine sulfide: Chem. Ib., 103, 2995 (1970).
Cim npe nrov: cas:1100-88-5|benzyltriphenylphosphonium chloride (bpp), nqe, hais, luv nqi, Tshuag, kev muag
Koj Tseem Yuav Zoo Li
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