CAS: 38465-86-0|1, 5-Cyclooctadienebis (methyldiphenylphosphine) iridium(I) Hexafluorophosphate
Cov mis mos molecular: C34H38F6IrP3
Molecular Luj: 845.79
Purity: 98 feem pua
Pob: 5g / 10g / 25g / 50g / bulk pob
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Lub npe | 1, 5-Cyclooctadienebis(methyldiphenylphosphine) iridium(I) hexafluorophosphate |
Synonyms | (1Z,5Z)-Cycloocta-1, 5-diene; iridium; methyl (diphenyl) phosphane; hexafluorophosphate |
CAS | 38465-86-0 |
MDL Nr | PAB 00064800 |
Melting Point | 224 degree dec. (Lit.) |
PSA | 40.77 |
LogP | 11.55 |
Qhov tshwm sim | Liab Crystalline hmoov |
rhiab heev | Cua & Moisture Sensitive |
Solubility | Soluble hauv acetone. Insoluble hauv dej |
Kev cia khoom | Hauv qab roj inert (nitrogen lossis Argon) ntawm 2-8 degree |
InChI | InChI=1S/2C13H13P.C8H12.F6P.Ir/c2*1-14(12-8-4-2-5-9-12)13-10-6-3-7-11-13;1-2-4-6-8-7-5-3-1;1-7(2, 3,4,5)6;/h2*2-11H,1H3;1-2,7-8H,3-6H2;/q;-1;/ b;2-1-,8-7- |
InChIKey | MUHONFFTSOCMDH-JXNOXZOESA-N |
Daim ntawv thov:
(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate(CAS: 38465-86-0) yog cationic Iridium (I) complex ua hauj lwm raws li ib tug catalyst. (1,5-Cyclooctadiene)bis (methyldiphenylphosphine) iridium(I) hexafluorophosphate tau ua haujlwm rau isomzerization ntawm allyl ethers ntawm glycerol thiab qabzib mus rau qhov sib thooj 1-propenyl ethers, thiab cov txheej txheem no tau pom siv hauv Lwm yam kev siv tshuaj lom neeg carbohydrate.
Cov ntaub ntawv:
1. Oltvoort, JJ, et al. 1981. Synthesis. Xyoo 1981: 305-308.
2. Spijker, NM, et al. 1996. Tetrahedron. 52: 3 :ua.
3. Petitou, M., et al. 2001. Chemistry Eur. J. 7: 858-873.
Cim npe nrov: cas:38465-86-0|1, 5-cyclooctadienebis (methyldiphenylphosphine) iridium(i) hexafluorophosphate, nqe, hais, luv nqi, hauv Tshuag, kev muag
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